Glacial Acrylic Acid

Glacial Acrylic Acid

Glacial Acrylic Acid (CAS No. 79-10-7) or 2-propenoic acid is the starting point for all acrylic chemistry. It can be reacted with alcohols to form esters know as acrylates. Acrylic acid and it's esters are used as the components for polymers used in adhesives, coatings, inks, plastics, elastomers, water treatment, personal care, and various other industries.
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Product Introduction
 
Why Choose Us
 
01/

Good Service
Mainly focused on every buyers demands, no matter big buyer or small buyer, and we will try best to meet most buyers needs, there is no MOQ there.

02/

Quality Assurance
Kaitai brand acrylic acid is well-known in China, and its application in the field of water reducing agent is one of the strongest brands.

03/

Rich Experience
Kaitai Petrochemical has nearly 20 years of development history and profound corporate culture.

04/

Fast Delivery
Shandong Kaitai never ceases its effort to serve customers, and sold acrylic acid esters to most parts of China and overseas.

What is Glacial Acrylic Acid

 

Glacial Acrylic Acid (CAS No. 79-10-7) or 2-propenoic acid is the starting point for all acrylic chemistry. It can be reacted with alcohols to form esters know as acrylates. Acrylic acid and it's esters are used as the components for polymers used in adhesives, coatings, inks, plastics, elastomers, water treatment, personal care, and various other industries. Glacial Acrylic Acid is highly susceptible to dimerization and must be handled with care. If frozen, extreme precaution should be taken to thaw the monomer to prevent a run away polymerization and potential explosion.

Acrylic Acid

Acrylic Acid

Acrylic acid is an organic compound that is the simplest unsaturated carboxylic acid and consists of a vinyl group attached directly to the carboxylic acid end. This colorless liquid has a characteristic pungent or sour taste. It is miscible with water, alcohols, ethers and chloroform.

Glacial Acrylic Acid

planning cepteur

Glacial acrylic acid (GAA) is a clear, colorless liquid with a pungent odor that is miscible with water, alcohols, and ethers. It is an unsaturated monocarboxylic acid that undergoes typical reactions of carboxylic acids and vinyl compounds. It is used to produce polymers and acrylates and as a raw material for chemical syntheses.
Glacial acrylic acid is used as an additive for various products due to its flexibility, good weather resistance, adhesion, abrasion resistance, and oil resistance.

Butyl Acrylate

Butyl Acrylate

Butyl acrylate (BA) is an organic compound with the molecular formula C4H9O2CCH=CH2. It is a colorless liquid, the butyl ester of acrylic acid. It is used commercially on a large scale as a precursor for poly(butyl acrylate). In particular, as copolymers, such materials are used in paints, sealants, coatings, adhesives, fuels, textiles, plastics, and caulks.
Butyl acrylate can be produced by the acid-catalyzed esterification of acrylic acid with butanol. It polymerizes readily, so commercial preparations contain polymerization inhibitors such as hydroquinone, phenothiazine, or hydroquinone ether.
Shandong Kaitai Petrochemical Acrylic Acid Ltd is one of the most professional glacial butyl acrylate manufacturing plants and suppliers in China, having been developed for more than 10 years. Kaitai's production site processes 80,000 MTS of manufacturing capacity of butyl acrylate per year. "Kaitai" brand butyl acrylate is mainly exported to India, Turkey, UAE, South Africa, etc.

methyl acrylate4

Methyl Acrylate

Methyl acrylate is an organic compound. It is a colorless liquid with a pungent odor. It is mainly used to make acrylic fibers. It is also a reagent for the synthesis of various pharmaceutical intermediates. Generally, methyl acrylate (and other acrylates) are copolymerized with other olefins to make useful engineering plastics.

 
Production Process of Glacial Acrylic Acid

 

Raw material preparation

Take crude acrylic acid aqueous solution as raw material.

01

Extraction

Add extractant for extraction to separate the aqueous phase from the organic phase. The purpose of this step is to keep the water-soluble impurities in the aqueous phase, while acrylic acid and other oil-soluble impurities are enriched in the organic phase.

02

Addition of inhibitors

Inhibitors are added to the organic phase to prevent polymerization of acrylic acid during storage and transportation.

03

Vacuum distillation

Separation of the extractant from the acrylic solution by vacuum distillation.

04

Melt crystallization

The obtained acrylic acid solution is subjected to melt crystallization to obtain high purity ice crystal acrylic acid.

05

 

The Difference Between Glacial Acrylic Acid and Acrylic Acid

 

 

Glacial acrylic acid (GAA): Usually refers to high purity acrylic acid, also known as ice crystal grade acrylic acid. This type of acrylic acid is of high purity and is suitable for specific industrial applications such as the production of highly absorbent resins (SAP), polymer electrolytes, functional monomers for polymer polymerization, organic synthesis, water treatments and paper chemicals.


Ordinary acrylic acid: Also known as technical grade acrylic acid, it is an important raw material for organic synthesis and a monomer for synthetic resins. It is a kind of vinyl monomer with very fast polymerization speed, mainly used in the preparation of acrylic resin and so on.

Application Areas of Glacial Acrylic Acid

Polymers and resins
Glacial acrylic acid is one of the important raw materials for the synthesis of polymers and resins such as poly(acrylic acid) (PAA), which has excellent water absorption, solubility and ion-exchange properties, and is commonly used in the preparation of highly absorbent materials, hydrogels and ion-exchange resins.


Coatings and adhesives
Ice acrylics can be used as a component of coatings and adhesives to provide adhesion and water resistance, meeting the needs of environmental protection and sustainable development.

Textiles

In the field of textiles, glacial acrylic acid can be used in finishing treatments to improve the moisture absorption and softness of textiles, such as the preparation of moisture-absorbing fibers, wet wipes and textile coatings.

Pharmaceuticals and Pesticides

Glacial acrylic acid also has application prospects in the field of medicine and pesticide, such as the preparation of drug slow-release systems, pesticide formulations and biopesticides.

Other fields

Glacial acrylic acid can also be used in electronic materials, water treatment agents, oil field chemicals and coating auxiliaries.

 

Storage Conditions of Glacial Acrylic Acid

1. Temperature control: Acrylic acid should be stored at temperatures between 14 ~ 30°C. Ideally, storage temperature should be controlled at about 20°C to inhibit dimerization. Above freezing, the lower the temperature, the more polymerization can be avoided.


2. Preventing polymerization: To prevent polymerization of acrylic acid, inhibitors such as 200 ppm hydroquinone monomethyl ether are commonly used. These inhibitors only work at room temperature and in the presence of oxygen, so acrylic acid should not be used in an inert atmosphere.


3. Avoid contamination: Acrylic acid should be kept free of contamination during storage because many substances, such as peroxides, nitrogen-containing compounds and polyvalent metal ions, can initiate polymerization.


4. Periodic inspection: Tanks, piping and portable tanks should be inspected periodically for polymerization. Agglomerates and small particles from polymerization may further initiate polymerization.


5. Prevent corrosion: Acrylic acid is highly corrosive to many metals such as unalloyed steel, copper, brass, etc. When these metals decompose, polyvalent polymerization can occur. Decomposition of these metals can produce polyvalent metal ions that can initiate polymerization reactions. Therefore, these metals should be avoided in the storage and transportation of acrylic.

 

Acrylic Acid

Things to Keep in Mind When Purchasing Glacial Acrylic Acid

Quality assurance: Ensure that the product has been certified and proven by the relevant authorities, such as ISO certificates and quality assurance certificates.


Anti-counterfeiting technology: Look for the unique identification code on the product package to prevent purchasing counterfeit products.


Manufacturer selection: Choose a manufacturer with strong technical strength, modernized production equipment and high service level.


Field application precautions: Including foundation treatment, construction environment, coating thickness, etc., to ensure the quality of the coating and the use of the effect.


Compliance with environmental regulations: The production and use of ice acrylics are regulated by environmental regulations to ensure that the production and use will not cause excessive impact on the environment, including waste water, waste gas and treatment and discharge requirements.

Safety standards

The production and use of glacial acrylic acid is subject to relevant safety standards, including safety requirements for storage and transportation, as well as workplace safety measures and protective equipment.

Registration and licensing

The manufacture and sale of Ice-Acrylic Acid may require registration and appropriate licenses, and these requirements may vary by region and country.

Labeling and packaging requirements

Packaging and labeling of Ice-Acrylic Acid needs to comply with requirements to ensure proper identification and safe use of the product.

Import and export restrictions

Some countries or regions may impose restrictions on the import and export of Ice-Acrylic Acid or require specific licenses.

 

Our Factory

 

Kaitai Petrochemical was founded in July 2004. With the strong support of all sectors of society, it established a subsidiary in Gaoqing County in 2011 and officially put into production in October 2013. Since 2018, Kaitai has newly put into operation the 180000 tons high-end white oil project of its subsidiary. Kaitai Petrochemical has developed into a diversified chemical group company.
Shandong kaitai is located in beautiful Qi ancient capital- Zibo, which enjoys superior geographic position and convenient traffic- north to Huanghe River, east to Qingdao port, and south to the Jinan airport, Shandong Kaitai never ceases its effort to serve customers, and sold acrylic acid esters to most parts of China and overseas. Kaitai is a comprehensive enterprise integrating acrylic acid, acrylic ester and white oil production.
Shandong Kaitai Petrochemical adheres to the enterprise tenet of "pursuing high-quality development of the enterprise, rewarding shareholders, "Constantly improve the happiness index of employees and take the road of common prosperity", implements sunshine management, develops with customers, grows with employees. Fulfill social responsibility and build a respected enterprise; Fulfill economic responsibilities, build an enterprise with good benefits and prospects, make employees rich together, have higher income, better welfare, more status and dignity, create a happy place, live better and realize the dream of Kaitai.
Shadong Kaitai has more than 1000 employees, including 200 with medium and senior professional titles. Shandong Kaitai was qualified to be national "three systems" certified enterprise; Shandong acrylate Engineering Technology Research Center; High tech enterprises in Shandong Province; Shandong honest enterprise; "Kaitai" acrylic acid is a famous brand product in Shandong Province. In 2019, the comprehensive strength of Kaitai ranked 42nd among the top 100 enterprises in Zibo.

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FAQ
 

Q: What is glacial acrylic acid?

A: Glacial acrylic acid (GAA) is an organic compound with the chemical formula C3H4O2. It is a colorless liquid with a pungent odor. It is an important chemical raw material and is widely used in polymers, resins, coatings, adhesives, textiles, medicines and pesticides.

Q: What are the main application areas of glacial acrylic acid?

A: The main application areas of glacial acrylic acid include:
Polymers and resins: used to prepare poly glacial acrylic acid (PAA) and other polymers, which have excellent water absorption, swelling and ion exchange properties.
Coatings and adhesives: as a component of coatings and adhesives, it provides adhesion and water resistance.
Textiles: used for textile finishing to improve the hygroscopicity and softness of textiles.
Medicines and pesticides: used to prepare products such as drug sustained-release systems, pesticide formulations and biopesticides.
Others: It can also be used in electronic materials, water treatment agents, oilfield chemicals and coating additives.

Q: Will glacial acrylic acid crystallize at low temperatures?

A: Yes, glacial acrylic acid is easy to crystallize at low temperatures, especially when the temperature is below 15°C. In order to avoid crystallization, water dilution can be used to reduce its crystallization tendency.

Q: How to prevent glacial acrylic acid from crystallizing during storage?

A: Methods to prevent glacial acrylic acid from crystallizing include:
Water dilution: By adjusting the ratio of acrylic acid to water, such as acrylic acid: water = 6:4, it will not crystallize above 0 degrees Celsius.
Insulation measures: Store in a warm room or take insulation measures, such as using an insulated box or wrapping the storage container with insulation materials.

Q: What is the production process of glacial acrylic acid?

A: The production process of glacial acrylic acid generally includes: raw material preparation (crude acrylic acid aqueous solution) → adding an extractant for extraction → separating the aqueous phase and the organic phase → adding an inhibitor to the organic phase → vacuum distillation → separating the extractant and acrylic acid solution → subjecting the obtained acrylic acid solution to melt crystallization → obtaining a high-purity glacial acrylic acid product.

Q: What regulations regulate the production and use of glacial acrylic acid?

A: The production and use of glacial acrylic acid is regulated by environmental protection regulations and safety standards, including requirements for the treatment and discharge of wastewater, waste gas and waste, as well as safety requirements for storage and transportation. In addition, production and sales may require registration and corresponding licenses.

Q: What is the market distribution of glacial acrylic acid?

A: The glacial acrylic acid market is widely distributed around the world, with major regions including Asia Pacific, Europe, North America and Latin America. Asia Pacific is the largest market, with China, India and Japan as major consumer countries.

Q: What are the dangers of glacial acrylic acid?

A: Ice-crystal acrylic acid belongs to Class 8 dangerous goods and is corrosive. Direct contact with the skin or eyes can cause severe chemical burns and pain, inhalation of its vapor may cause respiratory irritation and throat pain, and swallowing may cause chemical burns to the mouth, throat, stomach and intestines. Container rupture or leakage may cause serious harm to the surrounding environment.

Q: How to safely store and transport glacial acrylic acid?

A: When storing and transporting glacial acrylic acid, the container must be properly packaged, sealed and fixed to prevent it from being inhaled or contacting sensitive parts such as skin, eyes, and mouth. When the container is ruptured or leaked, rescue measures should be taken immediately and the leaked material should be properly cleaned up.

Q: What is the difference between glacial acrylic acid and acrylic acid?

A: Glacial acrylic acid is a specific form or product form of acrylic acid, which may refer to acrylic acid products that have been specifically treated or purified. Acrylic acid is a broader chemical substance with multiple uses and forms.

Q: What are the applications of glacial acrylic acid in the medical field?

A: In the medical field, glacial acrylic acid can be used to prepare drug sustained-release systems to help drugs slowly release over a specific period of time and improve the efficacy and safety of drugs.

Q: What are the application prospects of glacial acrylic acid in the field of pesticides?

A: Glacial acrylic acid has broad application prospects in the field of pesticides. It can be used to prepare biopesticides and pesticide formulations to improve the environmental protection and sustainability of pesticides.

Q: What factors affect the market price of glacial acrylic acid?

A: The market price of glacial acrylic acid is affected by many factors, including raw material costs, production costs, supply and demand, policies and regulations, and international market trends.

Q: How to improve the purity of glacial acrylic acid?

A: Methods to improve the purity of glacial acrylic acid include optimizing the production process, adopting efficient extraction and separation technologies, and strengthening quality control and testing.

Q: What are the applications of glacial acrylic acid in the field of environmental protection?

A: The application of glacial acrylic acid in the field of environmental protection includes the preparation of environmentally friendly coatings and adhesives, the development of environmentally friendly pesticides and biopesticides, etc., which will help promote the development of the environmental protection industry.

Q: What by-products are produced in the production process of glacial acrylic acid?

A: Some by-products may be produced in the production process of glacial acrylic acid, such as unreacted raw materials, catalyst residues, impurities generated by the reaction, etc. These by-products need to be recovered or disposed of through appropriate treatment methods.

Q: What are the applications of glacial acrylic acid in the field of electronic materials?

A: In the field of electronic materials, glacial acrylic acid can be used to prepare high-performance electronic materials, such as conductive films, insulating layers, etc., to improve the performance and reliability of electronic products.

Q: How to choose a suitable glacial acrylic acid supplier?

A: When choosing a suitable glacial acrylic acid supplier, factors such as the supplier's credibility, product quality, price, delivery time, and after-sales service need to be considered. It is recommended to conduct sufficient market research and comparison to select suppliers with good reputation and strength.

Q: What role does glacial acrylic acid play in textile finishing?

A: In the finishing of textiles, glacial acrylic acid can improve the hygroscopicity and softness of textiles, making textiles more comfortable and durable.

Q: What are the development trends of glacial acrylic acid production technology?

A: The development trends of glacial acrylic acid production technology include improving production efficiency, reducing production costs, optimizing production process, strengthening environmental protection and sustainable development. With the continuous advancement of science and technology and the improvement of environmental awareness, the production technology of glacial acrylic acid will be more efficient, environmentally friendly and sustainable in the future.

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